Broadening the reactivity spectrum of a phthalocyanine catalyst while suppressing its nucleophilic, electrophilic and radical degradation pathways.
نویسندگان
چکیده
A robust molecule that resists degradation via nucleophilic, electrophilic and radical attacks is described. Coordinated O(2) is reduced catalytically, producing efficiently thyil radicals in spite of the extreme electronic deficiency of the catalyst.
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عنوان ژورنال:
- Dalton transactions
دوره 40 19 شماره
صفحات -
تاریخ انتشار 2011